(E)-N-(1-Benzothiophen-3-ylmethylidene)-2,6-dimethylaniline
نویسندگان
چکیده
In the title compound, C(17)H(15)NS, the benzothio-phene residue and the substituted benzene ring are oriented at a dihedral angle of 61.99 (7)°. An inter-molecular C-H⋯π inter-action contributes to the stability of the crystal structure.
منابع مشابه
(Z)-2-[(E)-2-(1-Benzothiophen-3-ylmethylidene)hydrazin-1-ylidene]-1,2-diphenylethanone
The title compound, C(23)H(16)N(2)OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)° with the benzothio-phene system ring. The benzothio-phene system and the remaining phenyl ring make an angle of 12.71 (13)°. The conformation around the imine functions is E for the C=N bond towards the benzothio-phene system and Z for the C=N bond towards the benzoyl group....
متن کامل(Z)-N-{(E)-10-[(2,6-Diisopropylphenyl)imino]-9,10-dihydrophenanthren-9-ylidene}-2,6-dimethylaniline
The title compound, C(34)H(34)N(2), adopts a Z,E configuration with respect to the N=C-C=N backbone, with an N-C-C-N torsion angle of 41.1 (4)° The dihedral angle between the benzene rings in the 9,10-dihydro-phenanthrene moiety is 18.0 (1)°.
متن کامل4-Bromo-2,6-dimethylaniline
The asymmetric unit of the title compound, C(8)H(10)BrN, contains two independent mol-ecules. The Br, N and methyl group C atoms lie in the benzene ring planes. In the crystal structure, N-H⋯N hydrogen bonds link the mol-ecules.
متن کاملN 2,N 2′-Bis(pyridin-2-ylmethylidene)pyridine-2,6-dicarbohydrazide dimethylformamide monosolvate
In the crystal of the title compound, C(22)H(22)N(8)O(3), the dicarbohydrazide mol-ecules are linked into a chain along [010] by C-H⋯N inter-actions involving the pyridyl N atoms and aromatic C-H groups. The DMF mol-ecule is hydrogen bonded with the amide N-H via N-H⋯O inter-actions. C-H⋯O inter-actions also occur.
متن کامل[(E)-Oxido(pyridin-2-ylmethylidene)amine-κ2 N,N′][(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2 N,N′]silver(I) perchlorate–bis[(E)-N-(pyridin-2-ylmethylidene)hydroxylamine-κ2 N,N′]silver(I) (1/1)
In the title salt co-crystal, [Ag(C(6)H(5)N(2)O)(C(6)H(6)N(2)O)]ClO(4)·[Ag(C(6)H(6)N(2)O)(2)], the asymmetric unit comprises a [Ag(LH)(2)](+) cation, a perchlorate anion and a neutral (LH)AgL mol-ecule, where LH is pyridine-2-carboxaldoxime. Both silver-containing species feature N,N'-chelating LH and L ligands, which define an N(4) donor set that is highly distorted [dihedral angles between Ag...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012